| R | Date | Home | Score | Away | HT | Crowd | >2.5 | HT | FT | TV | Time | Rating | Ref. | Location | |
| 1 | 30.07.2006 | Motherwell | 1 - 2 | Rangers | 0-1 | 11'745 | Yes | 2 | 2 | 14:00 | 0 | 0 | |||
| 2 | 05.08.2006 | St Mirren | 2 - 0 | Motherwell | 1-0 | 5'036 | No | 1 | 1 | 15:00 | 0 | 0 | |||
| 3 | 12.08.2006 | Motherwell | 0 - 2 | Aberdeen | 0-1 | 5'186 | No | 2 | 2 | 15:00 | 0 | 0 | |||
| 4 | 19.08.2006 | Hibs | 3 - 1 | Motherwell | 1-0 | 13'274 | Yes | 1 | 1 | 15:00 | 0 | 0 | |||
| 5 | 26.08.2006 | Falkirk | 0 - 1 | Motherwell | 0-0 | 4'594 | No | X | 2 | 15:00 | 0 | 0 | |||
| 6 | 09.09.2006 | Motherwell | 1 - 4 | Inverness C T | 0-1 | 4'091 | Yes | 2 | 2 | 15:00 | 0 | 0 | |||
| 7 | 17.09.2006 | Motherwell | 0 - 1 | Hearts | 0-0 | 5'931 | No | X | 2 | 15:00 | 0 | 0 | |||
| 8 | 23.09.2006 | Dundee Utd | 1 - 1 | Motherwell | 0-0 | 5'036 | No | X | X | 15:00 | 0 | 0 | |||
| 9 | 30.09.2006 | Motherwell | 5 - 0 | Kilmarnock | 3-0 | 4'765 | Yes | 1 | 1 | 15:00 | 0 | 0 | |||
| 10 | 14.10.2006 | Motherwell | 2 - 1 | Dunfermline | 0-0 | 4'527 | Yes | X | 1 | 15:00 | 0 | 0 | |||
| 11 | 21.10.2006 | Celtic | 2 - 1 | Motherwell | 1-0 | 57'742 | Yes | 1 | 1 | 15:00 | 0 | 0 | |||
| 12 | 28.10.2006 | Rangers | 1 - 1 | Motherwell | 1-0 | 49'785 | No | 1 | X | 15:00 | 0 | 0 | |||
| 13 | 04.11.2006 | Motherwell | 0 - 0 | St Mirren | 0-0 | 5'337 | No | X | X | 15:00 | 0 | 0 | |||
| 14 | 11.11.2006 | Aberdeen | 2 - 1 | Motherwell | 0-0 | 10'527 | Yes | X | 1 | 15:00 | 0 | 0 | |||
| 15 | 18.11.2006 | Motherwell | 1 - 6 | Hibs | 0-4 | 6'190 | Yes | 2 | 2 | 15:00 | 0 | 0 | |||
| 16 | 25.11.2006 | Motherwell | 4 - 2 | Falkirk | 1-1 | 4'970 | Yes | X | 1 | 15:00 | 0 | 0 | |||
| 17 | 02.12.2006 | Inverness C T | 0 - 1 | Motherwell | 0-0 | 3'668 | No | X | 2 | 15:00 | 0 | 0 | |||
| 18 | 09.12.2006 | Hearts | 4 - 1 | Motherwell | 1-1 | 16'753 | Yes | X | 1 | 15:00 | 0 | 0 | |||
| 19 | 16.12.2006 | Motherwell | 2 - 3 | Dundee Utd | 0-2 | 4'420 | Yes | 2 | 2 | 15:00 | 0 | 0 | |||
| 20 | 23.12.2006 | Kilmarnock | 1 - 2 | Motherwell | 1-2 | 5'576 | Yes | 2 | 2 | 15:00 | 0 | 0 | |||
| 21 | 26.12.2006 | Dunfermline | 0 - 2 | Motherwell | 0-1 | 4'200 | No | 2 | 2 | 15:00 | 0 | 0 | |||
| 22 | 30.12.2006 | Motherwell | 1 - 1 | Celtic | 0-1 | 9'769 | No | 2 | X | 12:30 | 0 | 0 | |||
| 23 | 02.01.2007 | Motherwell | 0 - 1 | Rangers | 0-0 | 10'338 | No | X | 2 | 15:00 | 0 | 0 | |||
| 25 | 20.01.2007 | Motherwell | p.p. | Aberdeen | 15:00 | ||||||||||
| 26 | 27.01.2007 | Hibs | 2 - 0 | Motherwell | 0-0 | 142'800 | No | X | 1 | 15:00 | 0 | 0 | |||
| 27 | 10.02.2007 | Falkirk | 1 - 2 | Motherwell | 0-0 | 4'478 | Yes | X | 2 | 15:00 | 0 | 0 | |||
| 28 | 17.02.2007 | Motherwell | 1 - 0 | Inverness C T | 1-0 | 4'258 | No | 1 | 1 | 15:00 | 0 | 0 | |||
| 24 | 20.02.2007 | St Mirren | 0 - 0 | Motherwell | 0-0 | 3'576 | No | X | X | 19:45 | 0 | 0 | |||
| 29 | 05.03.2007 | Motherwell | - | Hearts | 19:45 | ||||||||||
| 30 | 10.03.2007 | Dundee Utd | - | Motherwell | 15:00 | ||||||||||
| 31 | 17.03.2007 | Motherwell | - | Kilmarnock | 15:00 | ||||||||||
| 32 | 31.03.2007 | Motherwell | - | Dunfermline | 15:00 | ||||||||||
| 33 | 07.04.2007 | Celtic | - | Motherwell | 15:00 |
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