| R | Date | Home | Score | Away | HT | Crowd | >2.5 | HT | FT | TV | Time | Rating | Ref. | Location | |
| 5 | 11.10.2006 | Andorra | 0 - 3 | FYR Macedonia | 0-3 | Yes | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Belarus | 4 - 2 | Slovenia | 1-2 | Yes | 2 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Belgium | 3 - 0 | Azerbaijan | 1-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Bosnia-Herzeg. | 0 - 4 | Greece | 0-1 | Yes | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Croatia | 2 - 0 | England | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | France | 5 - 0 | Faroe Islands | 2-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Georgia | 1 - 3 | Italy | 1-1 | Yes | X | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Iceland | 1 - 2 | Sweden | 1-1 | Yes | X | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Kazakhstan | 0 - 2 | Finland | 0-1 | No | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Liechtenstein | 0 - 4 | Denmark | 0-2 | Yes | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Luxembourg | 0 - 1 | Bulgaria | 0-1 | No | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Malta | 2 - 1 | Hungary | 1-1 | Yes | X | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Netherlands | 2 - 1 | Albania | 2-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | North. Ireland | 1 - 0 | Latvia | 1-0 | No | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Poland | 2 - 1 | Portugal | 2-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Rep. of Ireland | 1 - 1 | Czech Republic | 0-0 | No | X | X | 0 | 0 | |||||
| 5 | 11.10.2006 | Russia | 2 - 0 | Estonia | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Serbia | 3 - 0 | Armenia | 0-0 | Yes | X | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Slovakia | 1 - 4 | Germany | 0-3 | Yes | 2 | 2 | 0 | 0 | |||||
| 5 | 11.10.2006 | Turkey | 5 - 0 | Moldova | 3-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Ukraine | 2 - 0 | Scotland | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 11.10.2006 | Wales | 3 - 1 | Cyprus | 2-0 | Yes | 1 | 1 | 0 | 0 |