| R | Date | Home | Score | Away | HT | Crowd | >2.5 | HT | FT | TV | Time | Rating | Ref. | Location | |
| 5 | 21.11.2006 | AEK Athens | 1 - 0 | AC Milan | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 21.11.2006 | Arsenal | 3 - 1 | Hamburger SV | 0-0 | Yes | X | 1 | 0 | 0 | |||||
| 5 | 21.11.2006 | Benfica | 3 - 1 | Copenhague | 0-0 | Yes | X | 1 | 0 | 0 | |||||
| 5 | 21.11.2006 | Celtic | 1 - 0 | Manchester Utd | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 21.11.2006 | CSKA Moscow | 0 - 2 | FC Porto | 0-0 | No | X | 2 | 0 | 0 | |||||
| 5 | 21.11.2006 | Lille | 2 - 2 | Anderlecht | 0-0 | Yes | X | X | 0 | 0 | |||||
| 5 | 21.11.2006 | Real Madrid | 2 - 2 | Lyon | 0-0 | Yes | X | X | 0 | 0 | |||||
| 5 | 21.11.2006 | Steaua Bucarest | 1 - 1 | Dinamo Kiyev | 0-0 | No | X | X | 0 | 0 | |||||
| 5 | 22.11.2006 | Bordeaux | 3 - 1 | Galatasaray | 0-0 | Yes | X | 1 | 0 | 0 | |||||
| 5 | 22.11.2006 | Inter Milan | 1 - 0 | Sporting | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 22.11.2006 | Levski Sofia | 0 - 2 | Barcelona | 0-0 | No | X | 2 | 0 | 0 | |||||
| 5 | 22.11.2006 | Liverpool | 2 - 0 | PSV | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 22.11.2006 | Shakhtar | 1 - 0 | AS Roma | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 22.11.2006 | Sparta Moscow | 2 - 2 | Bayern Munchen | 0-0 | Yes | X | X | 0 | 0 | |||||
| 5 | 22.11.2006 | Valencia CF | 2 - 0 | Olympiakos | 0-0 | No | X | 1 | 0 | 0 | |||||
| 5 | 22.11.2006 | Werder Bremen | 1 - 0 | Chelsea | 0-0 | No | X | 1 | 0 | 0 |