| R | Date | Home | Score | Away | HT | Crowd | >2.5 | HT | FT | TV | Time | Rating | Ref. | Location | |
| 2 | 26.09.2006 | AEK Athens | 1 - 1 | Anderlecht | 1-1 | No | X | X | 0 | 0 | |||||
| 2 | 26.09.2006 | Arsenal | 2 - 0 | FC Porto | 1-0 | No | 1 | 1 | 0 | 0 | |||||
| 2 | 26.09.2006 | Benfica | 0 - 1 | Manchester Utd | 0-0 | No | X | 2 | 0 | 0 | |||||
| 2 | 26.09.2006 | Celtic | 1 - 0 | Copenhague | 1-0 | No | 1 | 1 | 0 | 0 | |||||
| 2 | 26.09.2006 | CSKA Moscow | 1 - 0 | Hamburger SV | 0-0 | No | X | 1 | 0 | 0 | |||||
| 2 | 26.09.2006 | Lille | 0 - 0 | AC Milan | 0-0 | No | X | X | 0 | 0 | |||||
| 2 | 26.09.2006 | Real Madrid | 5 - 1 | Dinamo Kiyev | 2-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 2 | 26.09.2006 | Steaua Bucarest | 0 - 3 | Lyon | 0-1 | Yes | 2 | 2 | 0 | 0 | |||||
| 2 | 27.09.2006 | Bordeaux | 0 - 1 | PSV | 0-0 | No | X | 2 | 0 | 0 | |||||
| 2 | 27.09.2006 | Inter Milan | 0 - 2 | Bayern Munchen | 0-0 | No | X | 2 | 0 | 0 | |||||
| 2 | 27.09.2006 | Levski Sofia | 1 - 3 | Chelsea | 0-1 | Yes | 2 | 2 | 0 | 0 | |||||
| 2 | 27.09.2006 | Liverpool | 3 - 2 | Galatasaray | 2-0 | Yes | 1 | 1 | 0 | 0 | |||||
| 2 | 27.09.2006 | Shakhtar | 2 - 2 | Olympiakos | 1-1 | Yes | X | X | 0 | 0 | |||||
| 2 | 27.09.2006 | Sparta Moscow | 1 - 1 | Sporting | 1-0 | No | 1 | X | 0 | 0 | |||||
| 2 | 27.09.2006 | Valencia CF | 2 - 1 | AS Roma | 2-1 | Yes | 1 | 1 | 0 | 0 | |||||
| 2 | 27.09.2006 | Werder Bremen | 1 - 1 | Barcelona | 0-0 | No | X | X | 0 | 0 |